There could be, but usually silicone is a selling point, so the ingredients label will make it as obvious as posible to let you know that the product contains silicone.
For example, Frizz Ease makes it no secret that it contains silicone: http://www.johnfrieda.com/products/produ
It supposedly has a blend of silicones, so I'd recommend reading that label and seeing if those ingredients are in other serums you look at.
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